Amine-boron-phosphorus-containing adducts



United States Patent 5 Claims. (Cl. 260-583) This is a division of application Ser. No. 325,446, filed Nov. 21, 1963, now Patent No. 3,325,261.

This invention relates to novel amine-boron-phosphoruscontaining adducts and to a hydrocarbon fuel composition containing same having excellent surface ignition properties. More particularly, the fuel is a leaded gasoline containing a combustion chamber deposit modifier which reduces surface ignition and other harmful effects brought about by the formation and laydown of deposits in the combustion chamber of a gasoline engine.

Most conventional gasolines contain an alkyl lead compound, such as tetraethyl lead and tetramethyl lead, as an antiknock compound to improve the octane level of the gasoline. During combustion, the alkyl lead compounds break down to lead oxide and lead salts and form deposits in the combustion chamber of the engine. These deposits interfere with proper engine operation. Specifically, the lead deposits which are characterized by a low ignition temperature become incandescent at engine operating temperatures. These glowing or incandescent deposits cause premature firing of the fuel-air mixture during the compression stroke of the combustion cycle resulting in uneven firing in the engine with concomitant loss of power and an audible rumble noise. This phenomenon is known as surface ignition. Combustion chamber deposits also seriously reduce the efficiency of sparkplugs even to the point of causing them to misfire cOmpIeteIy. This is a serious or critical defect particularly in the case of leaded gasoline for aircraft operation.

The formation of lead deposits in gasoline engines has been greatly reduced by employing scavenger agents in conventional leaded gasolines. Scavenger agents are compounds capable of reacting with the tetraalkyl lead compounds during combustion to produce volatile lead compounds. The principal scavengers in use are alkylene dihalides, such as ethylene dichloride, ethylene dibromide and their mixtures. These compounds bring about the formation of lead chloride and lead bromide which, being volatile, are substantially removed from the engine during the exhaust cycle. Unfortunately, minor amounts of the lead compounds remain deposited in the engine creating a surface ignition problem which is particularly serious for modern high compression engines.

Considerable research has been conducted to reduce or overcome the surface ignition problem caused by combustion chamber deposits. This has led to the discovery of certain phosphate esters which are effective in reducing surface ignition. Indeed, certain aryl phosphate esters have achieved some degree of commercial acceptance. The known phosphate esters, however, have harmful side effects on gasoline. The principal objectionable feature of these phosphate esters is that they lower the octane value of gasoline, a particularly serious drawback where ones object is to produce the highest quality gasoline on a competitive basis.

The present invention provides a novel class of amineboron-phosphorns-containing adducts and a leaded gas line containing said adducts which exhibits an outstanding reduction in surface ignition. The amine-boron-phos- 3,358,029 Patented Dec. 12, 1967 phorus-containing adducts are also useful for imparting extreme pressure and anti-wear properties to mineral lubricating oils and for improving the performance of metal cutting fluids.

A surprising feature of the invention is that the adducts are highly effective for inhibiting surface ignition at relatively low levels of concentration.

Another unexpected feature of the invention is that the adducts have no harmful or deleterious effect on the overall octane quality of gasoline.

The amine-boron-phosphorus-containing adduct of the invention is represented by the formula:

in which R is an aliphatic radical having from 8 to 30 carbon atoms, R is either hydrogen or an aliphatic radical having from 1 to 30 carbon atoms, y is an integer from 1 to 4 and the total number of carbon atoms in said adduct is at least 24. The motor fuel of the invention is a leaded gasoline containing a minor deposit modifying amount of the above described adduct. More particularly, the leaded gasoline will contain from about 0.01 to 1 theories of the adduct.

Amines which can be employed to prepare the adduct of the invention are amines having one or more aliphatic radicals in which at least one aliphatic radical has at least 8 carbon atoms. This requirement together with the requirement of at least 24 carbon atoms in the adduct is critical to insure the solubility of the adduct in a leaded gasoline. The effective amines correspond to the formula:

wherein R is an aliphatic radical having from 8 to 30 carbon atoms and R is hydrogen or an aliphatic radical having from 1 to 30 carbon atoms. R is generally a branched chain alkyl radical because of the ready availability of these materials. Preferably, R is a tertiary alkyl radical having from 12 to 30 carbon atoms.

Examples of specific effective amines include laurylamine, 2-ethylhexylamine, tri-n-octylamine, tn'decylamine, tetradecylamine, hexadecylamine, octadecylamine, eicosylamine, tricosylamine, nonacosylamine, methyldodecylamine, dimethyldodecylamine, methyloctadecylamine, and dimethyloctadecylamine. Particularly preferred amines are certain commercially available mixtures of tertiary alkyl primary amines. For example, a mixture of tertiary alkyl primary amines in which the alkyl radical comprises a mixture of alkyl groups having from 11 to 14 carbon atoms is available under the name Primene 8l-R. Another commercially available amine is the mixture of tertiary alkyl primary amines in which the alkyl radical comprises a mixture of alkyl groups having 18 to 24 carbon atoms sold under the name Primene JM-T.

The adducts of the invention are prepared by mixing from 1 to 4 moles of an aliphatic amine with a mole of boron phosphate. The reactants are generally heated at a moderate temperature from about to C. to effect formation of the adduct. The reaction is usually accomplished by refluxing the reactants in a solvent such as benzene or toluene to remove the associated water of crystallization, of the BPO the solvent being finally stripped off, using conventional methods, to recover the adduct.

Examples of adducts of the invention and the mole ratio of their component parts, i.e., of the amine and boron phosphate are given below:

0 Tri-n-octylamine, BPO 2:1

Tri-n-octylamine, BPO 4:1 Di-2-ethylhexylamine, BPO 4:1

The amine-boron-phosphorus-containing adduct of the invention is added to a motor fuel in the gasoline boiling range containing an antiknock amount of a tetraalkyl lead compound. The motor fuel may consist of any hydrocarbon fuel including paraffinic, naphthenic, and aromatic hydrocarbons or mixtures thereof suitable for use in an internal-combustion, spark-ignition engine. These fuels are derived by the distillation of crude oil, by the catalytic or thermal cracking of gas oils, by the alkylation of isoparaflins with olefins, or by the polymerization of olefins. The boiling point of the motor fuel or gasoline will generally be in the range from about 100 F. to about 450 F. The motor fuel of the invention will contain a tetraalkyl lead compound, such as tetraethyl lead, in a concentration from about 0.5 ml. to about 5 ml. or more per gallon of fuel. The motor fuel may also contain a number of additives conventionally employed in a gasoline, such as scavengers, antioxidants, stabilizers, dyes, and metal suppressors.

The amount of the phosphorus-containing adduct employed in the gasoline of the invention is expressed in terms of theories. One theory of the phosphorus-containing adduct is defined as the amount of the adduct which will provide sufiicient phosphorus to react stoichiometrically with the lead atoms in the tetraalkyl lead antiknock compound present to form the compound Pb (PO The adduct is blended into the leaded gasoline in a concentration ranging from about 0.01 theory to about 1 theory in accordance with the foregoing definition based on the lead content of the fuel. Concentrations between about 0.05 and 0.5 theory are in the preferred range for the suppression of surface ignition.

Gasoline containing the adduct of the invention was tested for effectiveness in a single cylinder CFR L-head engine with an 11.3/ 1 compression ratio. The engine was continuously run on the test fuel over a 20-hour test period during which time engine operation was alternated between a 50-second idle cycle (600 rpm.) and a ISO-second full throttle cycle (900 r.p.m.). The surface ignition count rate was obtained using an ionization gap (sparkplug) as the surface ignition pickup coupled to a recording counter device. The surface ignition rate is expressed as the number of counts per hour, the lower the count value the better the quality and performance of the fuel.

Tests were conducted using a high octane blended gasoline as the motor fuel. This gasoline containing 40% aromatic hydrocarbons boiled in the range of 97 to 373 F., had a research octane number of 101.5, and contained '3 ml. of TEL per gallon. The adduct of the invention was blended into the leaded gasoline to provide phosphorus in the amounts indicated as theories of phosphorus according to the foregoing definition.

Example I The adduct formed from Primene JM-T and boron phosphate in the mole ratio of 2:1 respectively was blended into the above described base fuel. In this test, the base fuel had a surface ignition count of 260. When 0.1 theory of the foregoing adduct was employed, the surface ignition count dropped to 165. At a concentration of 0.3 theory, the surface ignition count was 48.

Example 11 The adduct formed from tri-n-octylamine and boron phospate in the mole ratio of 2:1 respectively was blended in the base fuel having a surface ignition count level of 260. At a concentration of 0.3 theory for this adduct, the surface ignition count dropped to 55.

The adducts of the invention have given outstanding improvements inthe surface ignition of the leaded gasoline. This improvement was obtained without any loss or reduction in the octane value of the fuels tested. In contrast to the foregoing improvements, Primene JM-T and tri-n-octylamine adducts of phosphoric acid in the mole ratios of 3:1 respectively did not suppress the surface ignition of the base fuel.

Obviously, many modifications and variations of the invention as hereinbefore set forth may be made without departing from the spirit and scope thereof, and therefore, only such limitations should be imposed as are indicated in the appended claims.

We claim:

1. An amine-boron-phosphorus-containing adduct represented by the formula:

in which R is an aliphatic hydrocarbon radical having from 8 to 30 carbon atoms, R is selected from the group consisting of hydrogen and an aliphatic hydrocarbon radical having from 1 to 30 carbon atoms, y is an integer from 1 to 4 and the total number of carbon atoms in said adduct is at least 24.

2. An adduct according to claim 1 consisting of a primary amine and boron phosphate.

3. An adduct according to claim 1 consisting of a tertiary amine and boron phosphate.

4. An adduct according to claim 1 consisting of a C tertiary alkyl primary amine and boron phosphate in a 2:1 mole ratio respectively.

5. An adduct according to claim 1 consisting of tri-noctylamine and boron phosphate, in a 2:1 mole ratio respectively.

References Cited UNITED STATES PATENTS 4/ 1961 Thayer 4469 7/1962 Thayer 4476 X 

1. AN AMINE-BORON-PHOSPHORUS-CONTAINING ADDUCT REPRESENTED BY THE FORMULA 